Since the curing time for sealants is anywhere from 12-72 hours, then adding a second coat to make sure coverage is complete can not be a bad thing. Yes it would really be making one thicker coat, not two coats as the sealant has not really set itself up yet, but I believe that two overlapping coats are better than one, especially if you are doing a customer's car and you won't be able to add a second coat after the first is fully cured ...